Observable evidence that a chemical reaction has occurred
Question 1
Zinc granules are placed in dilute sulphuric acid. Bubbles rise through the liquid, and the gas collected burns with a pop sound. Which gas is it?
(a)Sulphur dioxide
(b)Oxygen
(c)Hydrogen
(d)Water vapour
Show answer
(c) Hydrogen
Zinc reacts with dilute sulphuric acid to form zinc sulphate and hydrogen gas. The bubbles are hydrogen produced by the reaction, not the liquid boiling. A gas that burns with a pop sound is hydrogen.
Question 2
A magnesium ribbon is rubbed with sandpaper and then burnt in air. Which observation shows that a chemical reaction has taken place?
(a)The white powder formed after the ribbon burns
(b)The length of the ribbon before it is burnt
(c)The ribbon turning shiny after it is rubbed with sandpaper
(d)The dull grey colour of the ribbon before it is rubbed
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(a) The white powder formed after the ribbon burns
Rubbing with sandpaper only removes the coating on the surface, so the ribbon looks shiny but no new substance is formed. The colour and the length of the ribbon before burning describe the starting state, not a change. When the ribbon burns, a white powder is left behind. This powder is a new substance, so a chemical reaction has taken place.
Balancing equations by conserving every kind of atom
Question 3
How many aluminium atoms and how many chlorine atoms are there on each side of 2Al + 3CuCl2 → 2AlCl3 + 3Cu?
(a)Al 3, Cl 6 on each side
(b)Al 2, Cl 6 on each side
(c)11 atoms in all on each side
(d)Al 2, Cl 3 on each side
Show answer
(b) Al 2, Cl 6 on each side
On the left, 2Al gives 2 aluminium atoms and 3CuCl2 gives 3 × 2 = 6 chlorine atoms. On the right, 2AlCl3 gives 2 aluminium atoms and 2 × 3 = 6 chlorine atoms. So each side has Al 2 and Cl 6.
Question 4
The equation 6Fe + 8H2O → 2Fe3O4 + 8H2 is balanced. What should be done before giving it as the final balanced equation?
(a)Change Fe3O4 to FeO
(b)Divide only the reactant coefficients by 2
(c)Divide every coefficient by 2
(d)Nothing; keep all coefficients as they are
Show answer
(c) Divide every coefficient by 2
The coefficients 6, 8, 2, 8 share a common factor of 2. Dividing every coefficient by 2 gives 3, 4, 1, 4 and preserves every atom balance. Changing Fe3O4 changes the substance.
Writing word, formula and complete chemical equations
Question 5
An equation is being balanced: Fe + H2O → Fe3O4 + H2. What may be changed to balance it?
(a)The state symbols written after each formula
(b)The subscripts inside a formula
(c)The coefficients written in front of the formulae
(d)The chemical names written in place of the formulae
Show answer
(c) The coefficients written in front of the formulae
Balancing changes how many units of each substance take part, not what the substances are. A coefficient stands before a formula and gives the number of units, so coefficients may be changed. A subscript is part of the formula: changing the 4 in Fe3O4 gives a different substance. State symbols show physical condition and do not change any atom count. So only the coefficients written in front of the formulae may be changed.
Question 6
Zinc reacts with sulphuric acid to form zinc sulphate and hydrogen. Which word equation represents this reaction?
Zinc and sulphuric acid are the starting substances, so they are the reactants and are written on the left of the arrow. Zinc sulphate and hydrogen are formed in the reaction, so they are the products and are written on the right. The word equation is Zinc + sulphuric acid → zinc sulphate + hydrogen.
Classifying reactions from changes in reactants and products
Question 7
Which equation shows a decomposition reaction?
(a)Zn + CuSO4 → ZnSO4 + Cu
(b)ZnCO3 → ZnO + CO2
(c)Na2SO4 + BaCl2 → BaSO4 + 2NaCl
(d)2Mg + O2 → 2MgO
Show answer
(b) ZnCO3 → ZnO + CO2
In ZnCO3 → ZnO + CO2 a single reactant breaks down into two products. That pattern is decomposition. Zn + CuSO4 → ZnSO4 + Cu is displacement. Na2SO4 + BaCl2 → BaSO4 + 2NaCl is double displacement. 2Mg + O2 → 2MgO is combination.
Question 8
In sunlight, silver chloride breaks down as 2AgCl → 2Ag + Cl2. This is a decomposition reaction. Which reactant-product pattern makes a reaction a decomposition reaction?
(a)One reactant forms two or more products
(b)Two or more products form, whatever the reactants are
(c)Two compounds exchange their parts
(d)One element replaces another element from its compound
Show answer
(a) One reactant forms two or more products
A decomposition reaction starts with a single reactant that breaks down into two or more products. Here one compound, AgCl, gives silver and chlorine. The count of products alone is not enough, because a double displacement also gives two products but starts with two compounds.
Combination reactions and exothermic energy release
Question 9
A reaction goes on only while energy is supplied to it from outside. What is such a reaction called?
(a)Combination
(b)Exothermic
(c)Endothermic
(d)Displacement
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(c) Endothermic
The reaction absorbs energy from its surroundings all the while it proceeds. Reactions in which energy is absorbed are called endothermic reactions. An exothermic reaction is the opposite: heat is given out along with the products, so it does not need energy to be supplied to keep going.
Question 10
Quicklime reacts vigorously with water. What forms, and is heat given out or taken in?
(a)Slaked lime, with heat given out
(b)Slaked lime, with heat taken in
(c)Slaked lime, only if the mixture is heated
(d)Calcium carbonate, with heat given out
Show answer
(a) Slaked lime, with heat given out
Quicklime is calcium oxide. It combines with water to give slaked lime, calcium hydroxide. The mixture becomes hot on its own, so heat is given out along with the product. The reaction is exothermic. No outside heating is needed and no heat is taken in. Calcium carbonate is not formed here.
Decomposition reactions driven by heat, light or electricity
Question 11
Electrolysis of water collects 20 mL of hydrogen and 10 mL of oxygen. Which explanation accounts for the larger hydrogen volume?
(a)2H2O → 2H2 + O2 produces hydrogen and oxygen in a 2:1 volume ratio.
(b)The 2:1 ratio occurs because oxygen is produced at twice hydrogen's volume.
(c)Only heating can decompose water, so electricity cannot account for either gas.
(d)Water electrolysis should give equal gas volumes; the readings must be wrong.
Show answer
(a) 2H2O → 2H2 + O2 produces hydrogen and oxygen in a 2:1 volume ratio.
The complete equation, observation, and reaction pattern determine the result. 2H2O → 2H2 + O2 produces hydrogen and oxygen in a 2:1 volume ratio.
Displacement reactions and relative reactivity
Question 12
Compare Fe + CuSO4 → FeSO4 + Cu with Na2SO4 + BaCl2 → BaSO4 + 2NaCl. Which comparison is correct?
(a)Both must occur because any metal can displace any other metal from a compound.
(b)The first is double displacement and the second is combination.
(c)The first is single displacement by a free element; the second is ion exchange between compounds.
(d)Both are exchanges between two compounds and therefore both are displacement reactions.
Show answer
(c) The first is single displacement by a free element; the second is ion exchange between compounds.
The complete equation, observation, and reaction pattern determine the result. The first is single displacement by a free element; the second is ion exchange between compounds.
Double displacement, ion exchange and precipitation
Question 13
Sodium sulphate solution is mixed with barium chloride solution. Name the precipitate and the product that stays in solution.
(a)Ba solid, NaCl aqueous
(b)BaSO4 solid, NaCl aqueous
(c)NaCl solid, BaSO4 aqueous
(d)BaSO4 solid only
Show answer
(b) BaSO4 solid, NaCl aqueous
Both reactants are in solution, so their ions exchange partners: Na2SO4(aq) + BaCl2(aq) gives BaSO4(s) + 2NaCl(aq). Barium sulphate is insoluble, so it separates as a white precipitate and is written (s). Sodium chloride is soluble, so it stays dissolved and is written (aq). Two products form, not one, and no free element is released. The answer is BaSO4 solid, NaCl aqueous.
Oxidation, reduction and paired redox change
Question 14
Hydrogen is passed over hot copper oxide. The black solid turns brown and water is formed. What happens to the copper oxide?
(a)It is oxidised
(b)It is first reduced and then oxidised
(c)It is neither oxidised nor reduced
(d)It is reduced
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(d) It is reduced
Copper oxide loses its oxygen to hydrogen, and the brown solid left behind is copper. Loss of oxygen is reduction, so the copper oxide is reduced. The hydrogen gains that oxygen and forms water, so hydrogen is oxidised. Both changes happen together in the same reaction.
Everyday oxidation: corrosion, rancidity and prevention
Question 15
A coat of paint is applied on an iron railing. Why does the paint stop the iron from rusting?
(a)It changes the rust already present back into iron.
(b)It makes the iron surface harder and stronger.
(c)It keeps air and moisture away from the iron.
(d)It removes all the oxygen from the surrounding air.
Show answer
(c) It keeps air and moisture away from the iron.
Iron rusts when its surface stays in contact with air and moisture. A coat of paint covers the surface and keeps air and moisture away from the iron, so rusting is prevented. Paint acts as a barrier only; it does not change rust back into iron.
Common misconception in Chemical Reactions and Equations
Write NH₃ as NH₆ to account for all six hydrogen atoms.
Why it feels right. I want more hydrogen atoms on the product side, so I change the subscript.
Right
A coefficient changes how many molecules you count. A subscript changes the formula.
Worked example
Reactants
NN
HH
HH
HH
Products
NHHH
NHHH
Two copies of NH₃ use all six hydrogen atoms without changing the ammonia formula.
In N₂ + 3H₂ → 2NH₃ there are 2 nitrogen and 6 hydrogen atoms on each side.
The coefficient 2 counts two ammonia molecules and keeps the formula NH₃.
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