Practice questions › Class 11 › Chemistry › Classification of Elements and Periodicity in Properties Mendeleev's predictions and the modern periodic law Question 1 Why did Mendeleev place iodine after tellurium despite their atomic weights?
(a) He always placed heavier elements first (b) That placement preserved similarity with the halogens (c) Iodine had no measured mass (d) Tellurium was an alkali metal Show answer (b) That placement preserved similarity with the halogens
Mendeleev prioritized recurring chemical properties over strict mass order.
Question 2 What did the gaps under aluminium and silicon represent?
(a) Predicted undiscovered elements (b) Spaces reserved for isotopes (c) Errors in printing the table (d) Elements known to be impossible Show answer (a) Predicted undiscovered elements
Eka-aluminium and eka-silicon were predictions later matched by Ga and Ge.
Need for classification and historical periodic schemes Question 3 Mendeleev's periodic law related properties primarily to what quantity?
(a) Atomic weight (b) Nuclear spin (c) Neutron number (d) Atomic number Show answer (a) Atomic weight
The historical law used atomic weight; atomic number became the modern basis.
Question 4 What evidence did Mendeleev use besides atomic weight?
(a) Only alphabetical order (b) Only colour of the free element (c) Only date of discovery (d) Similar formulas and chemical properties of compounds Show answer (d) Similar formulas and chemical properties of compounds
Chemical similarity determined vertical grouping and sometimes overrode strict mass order.
Electronic configuration, periodic position, and blocks Question 5 An element ends in 3s²3p⁴. Where is it located?
(a) Period 4, group 3, d block (b) Period 3, group 16, p block (c) Period 3, group 4, s block (d) Period 2, group 16, p block Show answer (b) Period 3, group 16, p block
Highest n is 3, the last subshell is p, and ns²np⁴ corresponds to group 16.
Question 6 How many columns are in the d block?
(a) 14 (b) 5 (c) 10 (d) 8 Show answer (c) 10
Five d orbitals accommodate ten electrons.
Periods, groups, and systematic element nomenclature Question 7 Using un=1, bi=2, nil=0, what is the temporary name for Z=120?
(a) Biniunium (b) Unbinilium (c) Ununbium (d) Unnilbium Show answer (b) Unbinilium
Concatenate the digit roots un-bi-nil and add ium.
Question 8 What is the systematic symbol corresponding to unbinilium?
(a) Un (b) Ub (c) Ubn (d) Ubi Show answer (c) Ubn
The symbol uses the initial of each of the three digit roots.
Block characteristics, metallicity, and second-period anomalies Question 9 Which property is common among many transition elements?
(a) They form only colourless ions (b) They are all noble gases (c) They have only s electrons (d) Variable oxidation states and catalytic behaviour Show answer (d) Variable oxidation states and catalytic behaviour
Partly filled d subshells support characteristic transition behaviour.
Question 10 Which d-block set is not typical of transition behaviour because of filled d subshells?
(a) Zn, Cd, and Hg (b) Sc, Ti, and V (c) Cr, Mn, and Fe (d) Fe, Co, and Ni Show answer (a) Zn, Cd, and Hg
Their common ions retain d¹⁰ configurations and lack many typical properties.
Atomic radius, ionic radius, and isoelectronic ordering Question 11 How is covalent radius estimated for a homonuclear single bond?
(a) The full bond distance (b) Half the internuclear distance (c) Twice the bond distance (d) The distance from nucleus to a sharp cloud edge Show answer (b) Half the internuclear distance
Electron clouds lack sharp edges, so an operational half-distance is used.
Ionization enthalpy, successive removal, and exceptions Question 12 Which process defines first ionization enthalpy?
(a) X(g) → X⁺(g) + e⁻ (b) X(s) → X⁺(aq) + e⁻ (c) X(g) + e⁻ → X⁻(g) (d) X⁺(g) + e⁻ → X(g) Show answer (a) X(g) → X⁺(g) + e⁻
The comparison uses isolated gaseous ground-state atoms.
Electron gain enthalpy and electronegativity Question 13 What does a negative electron gain enthalpy mean?
(a) Energy is released when the gaseous atom gains an electron (b) The electron has negative mass (c) Energy must be supplied (d) The atom loses an electron Show answer (a) Energy is released when the gaseous atom gains an electron
The sign follows the thermodynamic enthalpy change.
Valence, oxidation state, and periodic compound formulas Question 14 What formula is expected from aluminium and sulphur using Al³⁺ and S²⁻ tendencies?
(a) Al₃S₂ (b) Al₂S₃ (c) AlS (d) Al₂S Show answer (b) Al₂S₃
Two Al³⁺ and three S²⁻ give zero net charge.
Periodic reactivity and acidic-basic character of oxides Question 15 Why does group-1 reactivity increase down the group?
(a) Valence electron count rises from one to seven (b) Ionization enthalpy increases sharply (c) Increasing radius and shielding make electron loss easier (d) Atoms become smaller Show answer (c) Increasing radius and shielding make electron loss easier
Lower ionization enthalpy favours cation formation.
Does an atom get bigger as electrons are added across a period? Wrong
A chlorine atom is larger than a sodium atom because it has more electrons.
Why it feels right. I assume each extra electron adds another layer.
Right
Across Period 3, added valence electrons enter the same main shell as nuclear charge increases.
Worked example
Sodium Chlorine Both drawings represent Period 3 atoms. The smaller outline represents chlorine's smaller atomic radius. Sodium and chlorine both have their outermost electrons in the third shell. The greater effective nuclear attraction in chlorine pulls that shell closer, so chlorine has a smaller atomic radius. Previous chapter Structure of Atom Next chapter Chemical Bonding and Molecular Structure