Salt is added to water at a fixed temperature. After thorough stirring and enough time, some salt remains and no more dissolves. What is the state of the solution?
(a)It is saturated, and it can still dissolve a little more salt.
(b)It is saturated at this temperature.
(c)It is neither, because some salt did dissolve and some did not.
(d)Unsaturated, because that word means the maximum dissolved amount has been reached.
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(b) It is saturated at this temperature.
A solution that can still dissolve more solute at a given temperature is unsaturated. When the solute stops dissolving and begins to settle, no more will dissolve at that temperature, and the solution is saturated.
Uniform and non-uniform mixtures
Question 2
Sand is stirred into a glass of water and the glass is left standing. After a while a layer of sand is resting on the bottom and the water above it looks clear. What does the layer on the bottom tell us?
(a)The water has become heavier than the sand.
(b)The sand dissolved, and only the extra amount has settled out.
(c)The sand did not dissolve, so this is a non-uniform mixture.
(d)The mixture is uniform, and stirring it again would keep it that way.
Show answer
(c) The sand did not dissolve, so this is a non-uniform mixture.
The sand grains remain a separate solid phase and settle after stirring. In this sand-water case, settling shows a suspension rather than a solution.
What solute, solvent and solution are
Question 3
Sand remains undissolved after stirring in pure water. Has it formed a solution with sand as solute and water as solvent?
(a)No. The undissolved sand and water form a non-uniform mixture, not a solution.
(b)Yes. The settled sand is dissolved because it is still inside the water.
(c)The sand is the solute and the water is the solvent, as in every mixture.
(d)Sand is the solvent because it settles at the bottom.
Show answer
(a) No. The undissolved sand and water form a non-uniform mixture, not a solution.
Solute and solvent are the parts of a solution, and a solution is a uniform mixture. Sand does not dissolve in water: it separates out on standing, making a non-uniform mixture. So neither name applies here.
Which component is the solvent
Question 4
A cook dissolves more sugar by mass than water to make a syrup. Which component is the solvent, and why?
(a)Water, because water must be the solvent whenever present, even as the smaller component in any two-liquid solution.
(b)The sugar, because there is more of it than there is water.
(c)Sugar, because the component that dissolves must be called the solvent.
(d)The water, because a solid dissolving in a liquid makes the liquid the solvent.
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(d) The water, because a solid dissolving in a liquid makes the liquid the solvent.
The amount rule applies when both components are liquids. When a solid dissolves in a liquid, the states decide instead: the solid is the solute and the liquid is the solvent, however much of each there is.
Concentration: dilute and concentrated
Question 5
A solution is described as concentrated. Can any more solute dissolve in it?
(a)Possibly, since being concentrated does not mean the limit has been reached.
(b)No, because concentrated means no more solute will dissolve.
(c)Yes, and it will always take exactly one more spoonful.
(d)Yes, without any limit, because stirring can always dissolve unlimited solute.
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(a) Possibly, since being concentrated does not mean the limit has been reached.
Concentrated compares one solution with another; saturated names the point at which no more solute will dissolve at a given temperature. A concentrated solution may still be well short of that point.
Solubility
Question 6
A label reads: the solubility of this solid in water is 36 g per 100 g of water. Is that a complete statement?
(a)Yes, because solubility never needs a temperature.
(b)No, because the amount actually dissolved, rather than the maximum possible, defines solubility.
(c)Yes, as long as the water is pure.
(d)No, because a temperature must be given with it.
Show answer
(d) No, because a temperature must be given with it.
A solubility value describes the maximum dissolved amount for a specified solvent quantity and temperature. Temperature can change that maximum, so the label is incomplete.
Solubility of gases
Question 7
Only a very small amount of oxygen dissolves in water. Does that make the dissolved oxygen unimportant?
(a)No, because many fish depend on dissolved oxygen for breathing.
(b)No, but it counts as dissolved oxygen only when visible bubbles are present.
(c)Yes, because an amount that small can have no real effect.
(d)Yes, because the fish take their oxygen from the air above the water.
Show answer
(a) No, because many fish depend on dissolved oxygen for breathing.
Many fish obtain oxygen dissolved in water through their gills. A small dissolved amount can therefore be important for their survival.
Temperature and the solubility of solids
Question 8
Equal amounts of water are held at 20 degrees Celsius and at 70 degrees Celsius. Baking soda is added to each until no more will dissolve. Which water dissolved more?
(a)The water at 70°C, as in the chapter’s baking-soda comparison.
(b)Both dissolved the same amount, because heating does not change how much dissolves.
(c)The water at 20 degrees Celsius, because cold water is denser.
(d)The water at 20 degrees Celsius, because a solid dissolves more in colder water.
Show answer
(a) The water at 70°C, as in the chapter’s baking-soda comparison.
For most solids, solubility increases as the temperature rises. Water at 70 degrees Celsius therefore dissolves more baking soda than water at 20 degrees Celsius does.
The volume of regular and irregular solids
Question 9
Water stands at 60 mL. A 47 g stone is fully submerged without bubbles, absorption, or spillage; the reading becomes 71 mL. What is the stone’s volume?
(a)71 cm3
(b)47 cm3, because an object’s volume is the same quantity as its mass.
(c)60 cm3
(d)11 cm3
Show answer
(d) 11 cm3
The stone pushes aside its own volume of water, so the water rises by exactly that amount, whatever the stone weighs. Taking the first reading from the second gives 71 mL - 60 mL, and a volume of liquid in millilitres is written in cubic centimetres for a solid.
Measuring mass, and how mass differs from weight
Question 10
A watch glass is placed on a digital balance and the tare button is pressed. A sample is then placed on the watch glass. What does the balance now read?
(a)Zero, because taring cancels whatever is placed on the pan.
(b)The mass of the sample alone.
(c)The mass of the watch glass alone.
(d)The mass of the sample and the watch glass together.
Show answer
(b) The mass of the sample alone.
Pressing tare with only the container on the pan sets the display to zero, so the container no longer counts. Anything placed on it afterwards is what the balance then reads.
Choosing a measuring cylinder and its smallest reading
Question 11
You need to measure 70 mL in one filling. Which cylinder can hold enough and has the finest scale?
Cylinder capacity (mL)
Smallest division (mL)
50
1
100
1
250
2
500
5
(a)The 250 mL cylinder
(b)The 100 mL cylinder
(c)The 50 mL cylinder
(d)The 500 mL cylinder
Show answer
(b) The 100 mL cylinder
The 50 mL cylinder cannot hold 70 mL in one filling. Among the cylinders that can, the 100 mL cylinder has the smallest divisions.
Cylinder capacity
Smallest division
Can hold 70 mL?
50 mL
1 mL
No
100 mL
1 mL
Yes
250 mL
2 mL
Yes
500 mL
5 mL
Yes
Measuring the volume of a liquid
Question 12
Water is poured into a measuring cylinder. Its surface curves downwards in the middle. Where should the reading be taken, and from what position?
(a)Halfway between the highest and lowest points of the curve.
(b)At the highest point of the curve, with the eye level with it.
(c)At the lowest point of the curve, with the eye level with it.
(d)At the lowest point of the curve, from any convenient position.
Show answer
(c) At the lowest point of the curve, with the eye level with it.
For the concave water surface shown, read the lowest point of the meniscus. Keep your eye at that level to avoid a viewing-angle error.
Units of density and relative density
Question 13
The relative density of aluminium is 2.7. Which unit belongs with that figure?
(a)None, because relative density is a number with no unit.
(b)g/mL for a liquid and kg/m3 for a solid.
(c)kg/m3, because that is the SI unit of density.
(d)g/cm3, because that is the unit of density.
Show answer
(a) None, because relative density is a number with no unit.
Relative density is the density of a substance divided by the density of water at that temperature. Both are densities in the same unit, so the unit cancels and what is left is a plain number.
What density is
Question 14
One quantity tells us how much space an object occupies. What is that quantity called?
(a)Weight.
(b)Volume.
(c)Mass.
(d)Density.
Show answer
(b) Volume.
Mass is the quantity of matter in an object; volume is the space it occupies; density is the mass present in one unit of volume. The space occupied is the volume, and it is a different quantity from the mass.
Temperature and density
Question 15
A liquid-filled test tube has a stopper carrying an open thin tube, as shown. On warming, its liquid column rises without overflow or any liquid being added. What does this show?
(a)That the hot water has pushed the stopper down.
(b)That the liquid has become denser on being warmed.
(c)That the liquid has expanded, taking up more space than before.
(d)That more liquid has entered the test tube.
Show answer
(c) That the liquid has expanded, taking up more space than before.
In this setup, the rise shows expansion of the liquid. No liquid was added and none overflowed. The same sample takes up more space.
Common misconception in The Amazing World of Solutes, Solvents, and Solutions
When sugar dissolves, it stops adding to the mass.
Why it feels right. The sugar grains are gone from view.
Right
Dissolving spreads sugar through the water and preserves mass in a closed system.
Worked example
On the scale
Water and sugar separate→Stir in closed setup→Water and sugar mixed
Mass reading
Measure before→Same total after
The closed setup contains the same water and sugar before and after mixing.
Place water and still-unmixed sugar in separate cups inside a closed setup.
Weigh the full setup.
Mix the sugar into the water and weigh the full setup again.
The mass stays the same.
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